有機化学: 現在の研究
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概要

Production of Oxidant through Catalytic H₂O₂ Decomposition for NO Treatment

Jang JH and Han GB*

The NO oxidation process has been applied to improve a removal efficiency of NO included in exhaust gas. In this study, to produce a dry oxidant for the NO oxidation process, the catalytic H₂O₂ decomposition method was proposed. A variety of the heterogeneous solid-acidic Mn-based catalysts were prepared for the catalytic H₂O₂ decomposition and the effect of their physico-chemical properties on the catalytic H₂O₂ decomposition was investigated. The results of this study showed that the acidic sites of the Mn-based catalysts have an influence on the catalytic H₂O₂ decomposition. The Mn-based catalyst having the abundant acidic sites within the wide temperature range in NH₃-TPD shows the best performance for the catalytic H₂O₂ decomposition. Therefore, the NO oxidation efficiency, using the dry oxidant produced by the H₂O₂ decomposition over the Mn-based catalyst having the abundant acidic properties under the wide temperature range, was higher than the others. As a remarkable result, the best performances in the catalytic H₂O₂ decomposition and NO oxidation were shown when the Mn-based Fe₂O₃ support catalyst containing K component was used for the catalytic H₂O₂ decomposition.